Welcome to the forum, so glad you could join! : )
I hope I can help answer some of your questions.
First off you mentioned that you want to keep a couple. Sounds like an awesome idea, just make sure its legal first. Keeping wildlife, even common species, can be illegal in some states.
40 gallons is a pretty good size. Green frogs can get quite big, but for now they'll be fairly small "pollywogs" and you can always upgrade if need be. Splitting if half and half is smart. Frogs enjoy land, but they enjoy water even more, so perhaps a third land and two thirds water would be better. Also, make sure the water is deep enough they feel secure while in it. Shallow water will only make them antsy.
Place some floating plants, wood, or a shelf in the cage with the tadpoles. When they start to climb out onto these regularly, you can move them. At this point, they'll be breathing air and it will be important for them to have a perch they can rest on.
Best of luck! : )
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